1191 - Mentioned for the first time in a document of the Vatican, under the name "Cibinium" (due to the river Cibin that flows through the city)
1241 - Mongol victory over the Hungarian army, April 10
1292 - The first hospital in the Kingdom of Hungary was attested.
1380 - The first documented school in the Kingdom of Hungary.
1494 - The first pharmacy in the Kingdom of Hungary.
1534 - The first paper mill in the Kingdom of Hungary.
1544 - The first book in the Romanian language was printed in Sibiu, funded by John II Sigismund Zápolya. This was in Cyrillic letters.
1551 - Conrad Haas's experiment with rockets.
1570 - The Ottoman-dependent Principality of Transylvania was formed after the Ottoman conquest in Hungary.
1671 - Methane gas was discovered near Sibiu.
1782 - Franz-Joseph Müller von Reichenstein discovered the chemical element tellurium.
1788 - First theatre in Transylvania.
1795 - The first lightning rod in Transylvania and in Southeastern Europe was installed in Nagydisznód (present-day Cisnădie).
1817 - The Brukenthal Museum, the first museum in Transylvania was opened.
1867 - The Principality of Transylvania was reunited
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