The extraction of the quicksilver in the socavones (tunnels) was extremely difficult. Every day before the miners came down, a mass for the dead was celebrated. Due to the need of numerous hand-workers and the high rate of mortality, the Viceroy of Perù Francisco de Toledo resumed and improved the pre-Columbian mandatory service of the mita. Despite the risks, the mining attracted people from all over the Vice royalty. The allotted concession were rectangular, about 67x33m. Miners were divided in carreteros and barreteros.
Due to the discovery and then the extraction of the azogue (mercury) in a hill close to the actual location of the city, the Santa Barbara mine became famous in the new world and its activity led to the Viceroy of Peru, Francisco de Toledo, to establish the city in 1572 with the name of Villa Rica de Oropesa.
In 1648 the Viceroy of Peru, declared that Potosí and Huancavelica were "the two pillars that support this kingdom and that of Spain." Moreover, the viceroy thought that Spain could, if necessary, dispense with the silver from
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