The village was visited by the king of Portugal, John VI, in 1816, who also decreed its emancipation from Rio de Janeiro on 10 May 1819 and gave the new-created municipality a new name, Vila Real da Praia Grande (Royal Village of Long Beach).
In 1834, the city of Rio de Janeiro, capital of the newly established Empire of Brazil, was detached from the rest of Rio de Janeiro Province; Vila Real da Praia Grande was then chosen as the new capital of that province, while the city of Rio de Janeiro itself was converted into a neutral municipality, following the Ato Adicional. Niteroi served the function of capital till the year of 1975 – except for the period between 1894 and 1903 when it was temporarily transferred to the city of Petrópolis.
Vila Real da Praia Grande was officially renamed to Niterói on 6 March 1835
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